Hi Colin!
It sounds like our corp, South of Heaven, may be just what you’re looking for. We live on a High Sec island in Placid - High Sec surrounded by Low Sec. This gives us access to PvP in FW space and Null as well as safe High Sec PvE (missioning). We’re a casual group of working adults, and we like to split our time between low key PvE and isk making activities during the week and PvP on the weekend. We’re currently running a weekly PvP fleet on Saturdays at 0100 Eve time (900pm EST). Contact me if you’d like to know more - good luck!