Your question doesn’t really have enough information for someone to give you a valuable answer. Are you planning on hunting in lowsec or in nullsec? Do you prefer to try and destroy interceptors or asteros more, because if they are not trying to engage you, then you accomplish catching them in different ways. Is your intention to catch PVE or PVP pilots?
Smartbombs, as was suggested, will destroy some travel interceptors but generally not asteros if you’re solo. In lowsec you wont really “catch” an astero at a gate unless he makes a mistake or you’ve trashed-up the gate enough that he can’t cloak, and even then most will warp too quickly for you to catch. What I think you should consider is using an appropriate bait ship. There are lots of options and when it works it’s much more entertaining than a simple catch and kill anyway.