Only if you want to train certain skills faster. Look at the EVE University link that @Geo_Eclipse_Oksaras posted. Near the middle is a table that breaks down each group of skills into their Primary and Secondary attributes.
So for example, if you really wanted to train a lot of skills that under Gunnery and Missiles, you’ll see that the primary and secondary attributes are Perception (Primary) and Willpower (Secondary), which means they’ll benefit the most if Perception has the most amount of points in it, followed by Willpower.
The trade off here is that because putting points into Perception and Willpower would naturally reduce the points in the other attributes, skills that use the others (like Charisma or Memory) would train at a relatively slower rate.