You may want to look into my corporation, Cargo Sunesis Cult: Cargo Sunesis Cult - a place for you to excel! [HISEC - EU]
We like to help out new players and have multiple options for PvE. We have a friendly and tight knit community, albeit a tiny one at the moment. I have personally picked up multiple rookies, helped them with game mechanics, provided some free ships and many of them have progressed in just a couple weeks to flying various ships that cost up to hundreds of millions.
We have plans to get more and more active in PvP and build up some industry to support that. We also have some friends and connections to other, bigger corporations and alliances, so we’re not alone in what we do.